I got quite a lot
requests regarding a recipe for crystals made out of
"liquid blueing", charcoal, ammonia and table
salt.
However as I live in Germany I did not not have the
slightest clue what "blueing" is, as its not
used and not available in my country. So I did not have
any chance to grow some by myself.Now I can give you the following recipe
:
Making A Chemical Crystal Garden
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What You Need:
90 mL salt
90 mL liquid blueing
15 mL ammonia
An old pan
Vaseline
Pieces of coal or charcoal briquettes
Food colouring
What To Do:
Find an old pan and grease the edges with Vaseline (this
prevents the mixture from going over the edge).
Place a few pieces of coal or charcoal briquettes in the
pan.
Mix the salt, liquid blueing, and ammonia together.
Pour the salt mixture over the coal.
Dab drops of food colouring on top of the coal (you can
use a variety of colours).
Watch your garden grow. Be patient!
What's Going On?
The crystals are formed by salt molecules joining
together as the liquid evaporates into the air. The
ammonia helps to speed the rate of evaporation.
What Else You Can Do:
You can grow crystals of rock candy by dissolving sugar
in boiling water. Pour the hot water into a glass and
dangle a piece of string into the liquid. As the liquid
cools, sugar crystals appear on the string.
BE CAREFUL!
If you are making the sugar crystals, be sure to get an
adult to help, as boiling water can be dangerous.
Believe it or not there is a complete
website about liquid blueing and its US manufacturer and
they have a department about the crystals. Also if you
can not find their product in your local store, you can
find out where to buy it or order it direct. They even
have a complete crystal growing kit for sale.
Just check out
Mrs. Stewarts Liquid
Blueing
at

http://www.mrsstewart.com
Here is some additional
information which Richard Beckham sent in recently :
The manufacturer's
link on your web page describes the liquid blueing as
"extremely minute particles of blue powder (Ferric
Hexacyanoferrate)".
Translation: prussian blue (the stuff that makes blue
prints blue).
To make your own, add aqueous ferrous sulphate -
Fe(II)SO4 - to aqueous
potassium ferricyanide - K3Fe(III)(CN)6. The
insoluble blue precipitate (an
inorganic polymer of complex ions) will drop out
immediately. The principle
by-product will be aqueous potassium sulphate. Its
a pretty cool experiment
(I've performed it in the lab many times), worth trying
even if you don't
plan to make a crystal garden. The ammonia in the
recipe is required to
break the complex, allowing the iron salts to be
incorporated in the
resulting crystals. If you decide to try the
crystal garden, please let me
know how it turns out.
By the way, the blue color comes from the complex between
the ferrous and
ferric ion. On breaking the complex, the blue color
is lost. Hence, the
garden will have yellow and red colors typical of the
initial iron compounds
(as seen in the example picture on the manufacturer's web
page). Prussian
blue is considered a hazardous waste here in the States
(not very toxic to
humans, though).
If you have any
information about the crystal garden, experiences or may
be even pictures to share, please contact me under mr.bismuth@crystalgrowing.com !
© 2001 by
Udo J.A. Behner
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